adverstisement



SHERWIN-WILLIAMS CO -- 7894, GM BLUE ENGINE ENAMEL SPRAY PAINT -- 8010-00N080718
=====================  Product Identification  =====================

Product ID:7894, GM BLUE ENGINE ENAMEL SPRAY PAINT
MSDS Date:10/01/1992
FSC:8010
NIIN:00N080718
MSDS Number: CFSMM
=== Responsible Party ===
Company Name:SHERWIN-WILLIAMS CO
Address:101 PROSPECT AVE NW
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Info Phone Num:216-566-2902
Emergency Phone Num:216-566-2917
CAGE:54636
=== Contractor Identification ===
Company Name:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVE NW
Box:City:CLEVELAND
State:OH
ZIP:44115-1042
Country:US
Phone:800-251-2486/216-566-2242
CAGE:54636

=============  Composition/Information on Ingredients  =============

Ingred Name:PROPANE (PROPELLANT). VAPOR PRESSURE: 760 MMHG.
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 14%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT

Ingred Name:PROPANE, 2-METHYL-; (2-METHYLPROPANE (PROPELLANT)). VAPOR
    PRESSURE: 760 MMHG.
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: 14%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:TOLUENE (SARA 313) (CERCLA). VAPOR PRESSURE: 22 MMHG.
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 26%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:ACETONE (SARA 313) (CERCLA). VAPOR PRESSURE: 180 MMHG.
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 26%
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM; 1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:ETHYL 3-ETHOXYPROPIONATE. VAPOR PRESSURE: 1.1 MMHG.
CAS:83-69-9
Fraction by Wt: 4%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 2%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUPP DATA: MAY ALSO REQ TESTING FOR EXTRACTABILITY. DO NOT
    INCIN. DEPRESSURIZE CNTNR. DISP OF I/A/W FED, ST & LOC(ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: REGULATIONS REGARDING POLLUTION.
RTECS #:9999999ZZ

Ingred Name:EXPLO HAZ: REQS SPECIAL PRECS. DURING EMER CNDTNS OVEREXP
    TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9: BE IMMEDIATELY APPARENT. OBTAIN MEDICAL ATTENTION.
RTECS #:9999999ZZ

Ingred Name:OTHER PREC: GROUNDING PROCS. CONTENTS UNDER PRESS. DO NOT
    PUNCTURE, INCIN/EXPOS TO TEMPS ABOVE 120F. HEAT FROM (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11: SUNLIGHT, RADIATORS, STOVES, HOT WATER, & OTHER
    HEAT SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
    INTENTIONAL MISUSE BY DELIB CONC AND INHALING CONTENTS CAN BE(ING
    14)
RTECS #:9999999ZZ

Ingred Name:ING 15: HARMFUL/FATAL. COATING MAY CONTAIN MATLS CLASSIFIED
    AS NUISANCE PARTICULATES (LISTED "AS DUST" IN ING (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14: SECTION) WHICH MAY BE PRESENT AT HAZARDOUS LEVELS
    ONLY DURING SANDING/ABRADING OF DRIED FILM.
RTECS #:9999999ZZ

Ingred Name:HLTH HAZ: PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS MAY
    CAUSE ADVERSE EFFECTS TO LIVER, URINARY, BLOOD (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16: FORMING, CARDIO-VASCULAR, AND REPRODUCTIVE SYSTEMS.
    RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17: DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOSURE
    LEVELS ARE NOT ATTAINABLE IN WORKPLACE. REPORTS HAVE (ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18: ASSOC RPTD & PRLNGD OVEREXP TO SOLVS W/PERM BRAIN &
    NERV SYS DMG. TOLUENE APPEARS ON NAVY LISTING OF (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19: OCCUP CHEM REPROD HAZS. SEEK CONSULTATION FROM
    APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO(ING 21)
RTECS #:9999999ZZ

Ingred Name:ING 20: AND SAFE HANDLING AND EXPOSURE INFORMATION .
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:IRRIT OF EYES, SKIN & RESP SYSTEM. MAY
    CAUSE NERVOUS SYSTEM DEPRESSION. OVEREXPOSURE MAY RESULT IN
    UNCONSCIOUSNESS AND POSSIBLY DEATH. PROLONGED AND REPEATED EXPOSURE
    TO HEXANE MAY CAUSE DAMAGE TO NER VE TISSUE OF ARMS AND LEGS
    (PERIPHERAL NEUROPATHY), RESULTING IN MUSCULAR WEAKNESS AND LOSS OF
    SENSATION. (ING 16)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF
    COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OF
    SPRAY MISTS. REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE
    EYE OR EXCESSIVE SKIN EXPOSU RE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

=======================  First Aid Measures  =======================

First Aid:INHAL: REMOVE FROM EXPOS. RESTORE BREATHING. KEEP WARM AND
    QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
    REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYE: FLUSH
    WITH LARGE	AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL
    ATTENTION. INGESTION: NEVER GIVE ANYTHING BY MOUTH TO AN
    UNCONSCIOUS PERSON. DO NOT INDUCE VOMIT. GIVE SEVERAL GLASSES OF
    WATER. SEEK MED ATTN.

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.7%
Upper Limits:6%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
    EQUIPMENT . WATER SPRAY MAY BE INEFT. IF WATER USED, FOG NOZZ ARE
    PREF. WATER MAY BE USED TO COOL CLSD(SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
    HEAT, ELEC EQUIP, SPARKS, & OPEN FLAME. CLSD CNTNRS MAY EXPLODE
    WHEN EXPOS TO EXTREME HEAT. APPLIC TO HOT SURFS (ING 9)

==================  Accidental Release Measures  ==================

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
    REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAMMABLE. KEEP
    AWAY FROM HEAT, SPARKS, AND OPEN FLAME. VAPORS WILL ACCUMULATE
    READILY AND MAY IGNITE EXPLOSIVELY.
Other Precautions:DURING USE AND UNTIL ALL VAPORS ARE GONE: KEEP AREA
    VENT, DO NOT SMOKE, EXTING ALL FLAMES, PILOT LIGHTS, & HEATERS,
    TURN OFF STOVES, ELEC TOOLS & APPLIANCES, & ANY OTHER SOURCES OF
    IGNIT. CONSULT NFPA  CODE. USE APPRVD BONDING AND (ING 11)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
    APPLIC LIMITS BY VENT, WEAR NIOSH APPRVD PROPERLY FITTED ORGANIC
    VAP/PARTICULATE RESP FOR PROT AGAINST MATLS IN ING SECTION. WHEN
    SANDING, WIREBRUSHING, AB RADING, BURNING/WELDING DRIED (SUPDAT)
Ventilation:LOC EXHST PREFERABLE. GEN EXHST ACCEPTABLE IF EXPOS TO
    MATLS IN ING SECTION IS MAINTAINED BELOW APPLIC EXPOS (SUPDAT)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:USE ONLY WITH ADEQ VENT. AVOID BREATHING VAP
    AND SPRAY MIST. AVOID CONT WITH SKIN AND EYES. WASH HANDS AFTER
    USING.
Supplemental Safety and Health
FIRE FIGHT PROC: CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO
    WHEN EXPOS TO EXTREME HEAT. RESP PROT: FILM, WEAR NIOSH APPRVD
    PARTICULATE RESP FOR PROT AGAINST NON-VOLATILE MATLS IN ING SECTION
    . VENT: LIMITS. REFER TO OSHA STDS 1910.94, 1910.107, 1910.108.
    WASTE DISP METH: CONTAINING METHYL ETHYL KETONE (ING 7)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:<0F,<-18C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>75%

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
    MONOXIDE, OXIDES OF METALS IN INGREDIENTS SECTION.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA
    40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM APPLIC
    EPA HAZ WASTE NUMBERS. WASTE FROM PRODS CONTAINING LEAD/CHROMATE
    MUST ALSO BE TESTED  FOR EXTRACTABILITY. WASTE FROM PRODS (SUPDAT)

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 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.