adverstisement



DOW CHEMICAL U.S.A. -- DERAKANE 510A VINYL ESTER RESIN, 12247 -- 8030-00N001069
=====================  Product Identification  =====================

Product ID:DERAKANE 510A VINYL ESTER RESIN, 12247
MSDS Date:12/30/1988
FSC:8030
NIIN:00N001069
MSDS Number: BCGYG
=== Responsible Party ===
Company Name:DOW CHEMICAL U.S.A.
Address:CHEMICAL AND METALS DEPARTMENT
City:MIDLAND
State:MI
ZIP:48674
Country:US
Info Phone Num:517-636-4400
Emergency Phone Num:517-636-4400
CAGE:96717
=== Contractor Identification ===
Company Name:DOW CHEMICAL CO
Address:100 LARKIN CENTER
Box:City:MIDLAND
State:MI
ZIP:48674
Country:US
Phone:800-258-2436
CAGE:96717

=============  Composition/Information on Ingredients  =============

Ingred Name:ING 5:IARC. NEITHER DATA FROM VARIOUS LONG-TERM ANIMAL
    STUDIES NOR FROM EPIDEMIOLOGY OF WORKERS EXPOSED TO (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6:STYRENE PROVIDE ADEQ BASIS TO CONCLUDE THAT STYRENE
    IS CARCINOGENIC.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC:MD. IF LAVAGE IS PERFORMED, SUGGEST
    ENDOTRACHEAL &/OR ESOPHAGEAL CONTROL. DANGER FROM LUNG ASPIR (ING
    9)
RTECS #:9999999ZZ

Ingred Name:ING 8:MUST BE WEIGHED AGAINST TOX WHEN CONSIDERING EMPTYING
    STOM. NO SPEC ANTIDOTE. SUPPORTIVE CARE. TREATMENT (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9:BASED ON JUDGMENT OF MD IN RESPONSE TO REACTIONS OF
    PATIENT.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC:CHLORIDE/OTHER SOLVS IN CLEANUP POSES DISTINCT
    HAZ & THEREFORE SHLD BE AVOIDED. FOR LG SPILLS, (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11:EVACUATE UPWIND OF SPILLS & CONTAIN W/DIKE.
RTECS #:9999999ZZ

Ingred Name:RESP PROT:CONFINED/POORLY VENTED AREAS, USE APPRVD
    POS-PRESS SCBA.
RTECS #:9999999ZZ

Ingred Name:OTHER PROT EQUIP:ON OPERATION. EYE WASH FOUNTAIN SHOULD BE
    LOCATED IN IMMEDIATE WORK AREA.
RTECS #:9999999ZZ

Ingred Name:STYRENE  (SARA III). BP:>293F,>145C. VP:4.5 @ 20C. VAP
    DENS:3.6. LEL:1.1%. UEL:6.1%.
CAS:100-42-5
RTECS #:WL3675000
Fraction by Wt: 38%
OSHA PEL:100 PPM
ACGIH TLV:S,50PPM/100STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:BROMINATED VINYL ESTER RESIN
CAS:68140-84-1
Fraction by Wt: 62%

Ingred Name:SUPDAT:EYE IRRIT. STYRENE IS REPORTED TO HAVE CAUSED
    HEARING LOSS IN LAB ANIMALS UPON EXPOS TO HIGH CONCS (16 (ING 4)
RTECS #:9999999ZZ

Ingred Name:ING 3:TIMES TLV & HIGHER); HOWEVER, RELEVANCE OF THIS TO
    HUMANS IS UNKNOWN. FOR HAZ COMMUNICATION PURPOSES UNDER (ING 5)
RTECS #:9999999ZZ

Ingred Name:ING 4:OSHA STD 29 CFR PART 1910.1200 THIS MIXT CONTAINS
    COMPONENT (STYRENE) WHICH IS LISTED AS POTNTL CARCIN BY (ING 6)
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50:(ORAL,RAT) >4000 MG/KG.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:YES	 OSHA:NO
Health Hazards Acute and Chronic:EYE:MAY CAUSE MOD IRRIT. MAY CAUSE
    SLIGHT CORNEAL INJURY. VAPS MAY IRRIT. VAPS MAY CAUSE LACHRYMATION
    (TEARS). SKIN:PRLNG EXPOS NOT LIKELY TO CAUSE SIGNIFICANT IRRIT.
    MATL MAY STICK TO SKIN CAUSING IR RIT UPON REMOVAL. SINGLE PRLNG
    EXPOS ISNOT LIKELY TO RSLT IN MATL BEING ABSORBED THRU SKIN IN
    HARMFUL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:STYRENE:IARC GROUP 2B, VOLUME 7, PAGE
    345, 1987 .
Effects of Overexposure:HLTH HAZ:AMTS. INGEST:SINGLE ORAL DOSE TOX IS
    LOW. IF ASPIR (LIQ ENTERS LUNG), MAY BE RAPIDLY ABSORBED THRU LUNGS
    & RSLT IN INJURY TO OTHER BODY SYS. INHAL:EXCESS VAP CONCS ARE
    ATTAINABLE & COULD BE H AZ ON SINGLE EXPOS. SIGNS & SYMPS OF EXCESS
    EXPOS MAY BE ANESTH/NARC EFTS. EXCESS EXPOS MAY CAUSE IRRIT TO
    UPPER(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:EYES:IRRIGATE W/FLOWING WATER IMMED & CONTINUOUSLY FOR @ LST
    15 MINS. CONSULT MED PERS. SKIN:WASH OFF IN FLOWING WATER/SHOWER.
    INGEST:DO NOT INDUCE VOMIT. CALL MD &/OR TRANSPORT TO EMER FACILITY
    IMMED . INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE
    MOUTH-TO-MOUTH RESUSCITATION. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL
    MD. NOTE TO MD:DECISION WHETHER TO INDUCE VOMIT/NOT SHLD BE MADE BY
    ATTENDING (ING 8)

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:76.0F,24.4C
Lower Limits:SEE ING 1
Upper Limits:SEE ING 1
Extinguishing Media:WATER FOG, FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
    PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:KEEP AWAY FROM POSS IGNIT SOURCES SUCH AS
    OPEN FLAMES & SPK-PRDCG EQUIP. POLYMERIZATION UNDER INTENSE HEAT
    CNDTNS COULD CAUSE DRUMS TO RUPTURE.

==================  Accidental Release Measures  ==================

Spill Release Procedures:TREAT AS FLAMM LIQ. KEEP HEAT, FLAME/SPK PRDCG
    EQUIP AWAY. PROT PERS FROM STYRENE VAPS. SOAK UP SPILLS IN ABSORB
    MATL SUCH AS SAND & COLLECT IN SUITABLE CNTNRS. RESIDUAL RESIN MAY
    BE REMOVED USING STE AM OF HOT SOAPY WATER. USE OF METHYLENE(ING
    11)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:PRACTICE CARE & CAUTION TO AVOID SKIN
    & EYE CONTACT. AVOID INHALATION OF VAPORS.
Other Precautions:FOR ADDITIONAL PRECAUTIONS, SEE DOW BULLETIN,
    DERAKANE (R) VINYL ESTER RESINS - FABRICATING TIPS.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:USE NIOSH/MSHA APPRVD RESP. SELECTION OF
    AIR-PURIFYING/SUPPLIED-AIR WILL DEPEND ON SPEC OPERATION & POTNTL
    AIRBORNE CONC OF MATL. FOR EMER & OTHER CNDTNS WHERE EXPOS
    GUIDELINE MAY BE GREATLY EXCEEDED,	USE APPRVD POS-PRESS SCBA. IN
    (ING 13)
Ventilation:PROVIDE GENERAL &/OR LOCAL EXHAUST VENTILATION TO CONTROL
    AIRBORNE CONCS BELOW RECOM EXPOSURE GUIDELINE.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEM WORK GOG & FULL LGTH FCSHLD .
Other Protective Equipment:USE PROT CLTHG IMPERVIOUS TO THIS MATL.
    SELECTION OF SPEC ITEMS SUCH AS BOOTS, APRON/FULL-BODY SUIT WILL
    DEPEND (ING 14)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
HAZ DECOMP PROD:MAY BE EVOLVED. CNDTNS (POLYM):INHIBITOR & OXYGEN
    LEVELS. AVOID EXPOS TO DIRECT SUNLIGHT/TEMPS >120F(49C). EFTS OF
    OVEREXP:RESP TRACT. SYSTEMIC & OTHER EFTS:RPTD EXCESS EXPOS TO HIGH
    A MTS MAY CAUSE CNS, LIVER, KIDNEY EFTS &RESP/EYE IRRIT. RPTD
    EXCESS EXPOS TO SML AMTS MAY CAUSE CNS EFTS & RESP/ (ING 3)

==================  Physical/Chemical Properties  ==================

HCC:F4
Boiling Pt:B.P. Text:SEE ING 1
Vapor Pres:SEE ING 1
Vapor Density:SEE ING 1
Spec Gravity:1.17-1.22
Solubility in Water:VERY SLIGHT
Appearance and Odor:AMBER LIQUID - STYRENE ODOR

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIAL
Stability Condition to Avoid:AVOID STORAGE AT TEMPERATURES >120F, 49C
    OR IN DIRECT SUNLIGHT.
Hazardous Decomposition Products:UNDER CNDTNS OF IMPERFECT
    COMBUST/PYROLYSIS, VARIOUS PHENOLIC &/OR BROMINATED CMPDS, SUCH AS
    HYDROGEN BROMIDE, (SUPDAT)
Conditions to Avoid Polymerization:AVOID CONT W/METAL SALTS SUCH AS
    FERRIC & ALUMINUM CHORIDES, UNINTENDED CONT W/PEROXIDES & DEPLETION
    OF (SUPDAT)

====================  Disposal Considerations  ====================

Waste Disposal Methods:RESINS CAN BE DISPOSED OF THROUGH BURNING IN
    ADEQUATE INCINERATOR W/HALOGEN SCRUBBER, OR BURYING IN LANDFILL
    APPROVED FOR HALOGENS, I/A/W FEDERAL, STATE & LOCAL REGULATIONS.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.