adverstisement



HENKEL CORP -- ALODINE 1202 THIXOTROPIC POWDER, 234119 -- 8030-01-069-3030
=====================  Product Identification  =====================

Product ID:ALODINE 1202 THIXOTROPIC POWDER, 234119
MSDS Date:06/21/1994
FSC:8030
NIIN:01-069-3030
MSDS Number: CCBGB
=== Responsible Party ===
Company Name:HENKEL CORP
Address:32100 STEPHENSON HWY
City:MADISON HEIGHTS
State:MI
ZIP:48071
Country:US
Info Phone Num:810-583-9300
Emergency Phone Num:800-424-9300 (CHEMTREC)
Preparer's Name:S WHITNEY
CAGE:71410
=== Contractor Identification ===
Company Name:HENKEL CORP
Address:32100 STEPHENSON HIGHWAY
Box:City:MADISON HEIGHTS
State:MI
ZIP:48071
Country:US
Phone:215-628-1000
CAGE:71410

=============  Composition/Information on Ingredients  =============

Ingred Name:CHROMIUM (VI) OXIDE (1:3); (CHROMIC ACID (DRY)); LD50 (ORAL
    RAT): 51.10 +/- 5.93 MG/KG
CAS:1333-82-0
RTECS #:GB6650000
Fraction by Wt: 10-30%
OSHA PEL:0.5 MG CR/M3
ACGIH TLV:0.05 MG CR/M3

Ingred Name:ZIRCONATE (2-), HEXAFLUORO-, DIPOTASSIUM; (POTASSIUM
    FLUOZIRCONATE) (CERCLA)
CAS:16923-95-8
RTECS #:ZH7028400
Fraction by Wt: 1-10%
OSHA PEL:5 MG (ZR)/M3
ACGIH TLV:5MG(ZR)/M3/10STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:FERRATE (3-), HEXACYANO-, TRIPOTASSIUM; (POTASSIUM
    FERRICYANIDE)
CAS:13746-66-2
RTECS #:LJ8225000
Fraction by Wt: 1-10%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SODIUM FLUORIDE (CERCLA); LD50 (ORAL RAT): 80 MG/KG
CAS:7681-49-4
RTECS #:WB0350000
Fraction by Wt: 1-10%
OSHA PEL:2.5 PPM (F)
ACGIH TLV:2.5 MG (F/)M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:BORATE (1-), TETRAFLUORO-, POTASSIUM; (POTASSIUM
    FLUOBORATE)
CAS:14075-53-7
RTECS #:ED2800000
Fraction by Wt: 1-10%
OSHA PEL:2.5 MG/M3 (MFR)
ACGIH TLV:2.5 MG/M3 (MFR)

Ingred Name:VOLATILE ORGANIC COMPOUND: NONE
RTECS #:9999999VO
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:EFTS OF OVEREXP: CHRONIC: PRLNG/RPTD SKIN CONT MAY CAUSE
    "CHROME SORES". LONG-TERM EXPOS CAN CAUSE LIVER DMG, (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: KIDNEY DMG & DERM. PRLNG/RPTD INHAL OF MIST MAY
    CAUSE ULCERATION & PERFORATION OF THE NASAL SEPTUM. (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: CONTAINS FLUORIDES. EXPOSURE TO FLUORIDES OVER YEARS
    MAY CAUSE FLUOROSIS.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: IF RESP STOPS, GIVE MOUTH-TO-MOUTH
    RESUSCITATION. GET MED ATTN. INGEST: DO NOT INDUCE VOMIT. (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: DRINK LARGE QUANTITIES OF WATER. IF VOMITING
    OCCURS, DRINK MORE WATER. GET MEDICAL ATTENTION. (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
    PERSON.
RTECS #:9999999ZZ

Ingred Name:OTHER PROT EQUIP: RUBBER APRONS, BOOTS SHOULD BE USED AS
    NECESSARY TO PREVENT SKIN CONTACT.
RTECS #:9999999ZZ

Ingred Name:EYE PROTECTION: AND FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:YES    IARC:YES	  OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: CONT MAY RSLT IN LOSS OF
    VISION W/SEV BURNS. SKIN: CHROMIC ACID MAY BE ABSORBED THRU SKIN,
    ESP IF SKIN IS DAMAGED. FATAL KIDNEY DMG WAS REPORTED IN A PERS WHO
    EVIDENTLY ABSORBED CHROMIUM  TRIOXIDE INTO THE BODY. CONT W/SKIN
    CANCAUSE BURNS. SKIN ABSORPTION: PLEASE REFER TO SKIN CONT. (EFTS
    OF OVEREXPOSURE)
Explanation of Carcinogenicity:CHROMIUM (VI) OXIDE (1:3): IARC MONO ON
    EVAL OF CARCIN RISK OF CHEMICALS TO MAN, VOL 49, PG 49, 1990: GROUP
    1. (SUP DAT)
Effects of Overexposure:HLTH HAZ: INHAL: INHAL OF DUST/MIST MAY CAUSE
    IRRIT OF THE NASAL SEPTUM & RESP TRACT. PRLNG/RPTD EXPOS MAY CAUSE
    ULCERATION & PERFORATION OF THE NASAL SEPTUM. MAY CAUSE LIVER DMG.
    INGEST: CAN RSLT IN  GI DMG; BURNS OF THE DIGESTIVE TRACT. CHROMIC
    ACID IS CONSIDERED VERY TOX. SODIUM FLUORIDE IS TOX. (ING 7)
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF ASTHMA,
    ALLERGIES OR KNOWN SENSITIZATION TO CHROMIC ACID OR CHROMATES.

=======================  First Aid Measures  =======================

First Aid:EYES: IMMED FLUSH IN A STREAM OF WATER FOR AT LEAST 15 MIN
    WHILE FORCIBLY HOLDING EYELIDS APART TO ENSURE THOROUGH RINSING OF
    ALL EYE & LID TISS. GET MED ATTN. SKIN: IMMED REMOVE & DISCARD
    CONTAM CLTH G & SHOES. FLUSH SKIN THORO W/WATER FORAT LEAST 15 MIN.
    IF IRRIT PERSISTS, GET MED ATTN. INHAL: REMOVE TO FRESH AIR &
    REMOVE CONTAM CLTHG. IF BRTHG IS DFCLT, ADMIN OXYGEN. (ING 10)

=====================  Fire Fighting Measures  =====================

Extinguishing Media:AS REQUIRED TO ENTINGUISH SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:CLTHG CONTAM W/THE CHEM IS DANGEROUSLY
    FLAMM. IMMED REMOVE & RINSE THORO W/WATER. CONT W/COMBUST MATL MAY
    CAUSE FIRE. VIOLENT RXNS MAY OCCUR W/ORG (SUP DAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATORY PROTECTION.
    SWEEP UP OR OTHERWISE COLLECT AND STORE IN A SUITABLE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:KEEP SEPARATE FROM ORGANIC MATERIALS
    AND REDUCING AGENTS. DO NOT BREATHE DUST OR GET IN EYES, ON SKIN,
    OR ON CLOTHING.
Other Precautions:FOR INDUSTRIAL USE ONLY. CONTACT WITH COMBUSTIBLE
    MATERIAL MAY CAUSE FIRE.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH APPROVED DUST FILTER MASK OR RESPIRATOR IF
    DUSTING OCCURS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
    EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:CHEMICAL-RESISTANT SUCH AS BUTYL RUBBER.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 14)
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
    ANSI DESIGN CRITERIA . IMPERVIOUS PROTECTIVE CLOTHING SUCH AS (ING
    13)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: MATLS/REDUCING AGENTS. UNDER FIRE CNDTNS, DECOMP MATL MAY
    FORM A HOT VISCOUS FOAM. HAZ DECOMP PROD: FERRICYANIDE CAN EMIT
    FUMES OF CYANIDE. EXPLAN OF CARCIN: NTP 7TH ANNUAL RPT ON CARCINS, 
    1994: KNOWN TO BE CARCIN. HUMAN: LUNG TUMORS. WASTE DISP METH:
    APPLIC FED, STATE & LOC REGULATIONS.

==================  Physical/Chemical Properties  ==================

Solubility in Water:APPRECIABLE
Appearance and Odor:ORANGE POWDER, WITH BLAND ODOR

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ORGANIC MATERIALS, PAINT THINNERS OR REDUCING AGENTS.
Stability Condition to Avoid:AVOID HEAT AND OPEN FLAMES.
Hazardous Decomposition Products:THERMAL DECOMP MAY PRDCE HYDROGEN
    FLUORIDE. WHEN HEATED TO DECOMP/ON CONT W/STRONG ACIDS, POTASSIUM
    (SUP DAT)

====================  Disposal Considerations  ====================

Waste Disposal Methods:THIS CHEM CONTAINS CHROMIUM CMPDS & FLUORIDE
    CMPDS. WASTE TREATMENT & NEUT MAY BE REQUIRED PRIOR TO DISCHARGE TO
    SEWER. HAZ WASTE CHARACTS: EP TOX, TITLE 40, CODE OF FED REGS,
    261.24, HAZ WASTE NUMBER  D007. DISP OF IN COMPLIANCE W/ALL
    (SUPDAT)

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