adverstisement



DOW CHEMICAL U.S.A. -- DERAKANE 411-350PA VINYL ESTER RESIN, 14262 -- 6810-00N017676
=====================  Product Identification  =====================

Product ID:DERAKANE 411-350PA VINYL ESTER RESIN, 14262
MSDS Date:05/31/1989
FSC:6810
NIIN:00N017676
MSDS Number: BLZMQ
=== Responsible Party ===
Company Name:DOW CHEMICAL U.S.A.
Address:2020 DOW CENTER
City:MIDLAND
State:MI
ZIP:48640-6030
Country:US
Info Phone Num:517-636-4400
Emergency Phone Num:517-636-4400
CAGE:96717
=== Contractor Identification ===
Company Name:DOW CHEMICAL CO
Address:100 LARKIN CENTER
Box:City:MIDLAND
State:MI
ZIP:48674
Country:US
Phone:800-258-2436
CAGE:96717

=============  Composition/Information on Ingredients  =============

Ingred Name:SPILL PROC:SOLVENTS ARE NOT RECOMMENDED FOR CLEANUP UNLESS
    THE RECOMMENDED EXPOSURE GUIDELINES AND SAFE HANDLING (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: PRACTICES FOR THE SPECIFIC SOLV ARE FOLLOWED.
    CONSULT APPROPRIATE SOLVENT MSDS FOR HANDLING INFORMATION (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: AND EXPOSURE GUIDELINES. FOR LARGE SPILLS: EVACUATE
    UPWIND OF SPILLS AND CONTAIN WITH DIKE.
RTECS #:9999999ZZ

Ingred Name:CONDITIONS TO AVOID: INHIBITOR LEVELS. AVOID EXPOSURE TO
    SUNLIGHT OR TEMPERATURES ABOVE 120 F, 49 C.
RTECS #:9999999ZZ

Ingred Name:STYRENE. BP=294 F, 146 C. VAP PRESS=7 @20C. VAP DENS: 3.6.
    LEL: 0.88 %. UEL: 6.8 %.
CAS:100-42-5
RTECS #:WL3675000
Fraction by Wt: 35-50%
OSHA PEL:100 PPM
ACGIH TLV:S,50PPM/100STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:VINYL ESTER RESIN
CAS:36425-15-7
Fraction by Wt: BAL.

Ingred Name:FIRST AID PROC: WHETHER TO INDUCE VOMITING OR NOT SHOULD BE
    MADE BY THE ATTENDING MD. IF LAVAGE IS PERFORMED (ING 4)
RTECS #:9999999ZZ

Ingred Name:ING 3: SUGGEST ENDOTRACHEAL &/OR ESOPHAGEAL CONTROL. DANGER
    FROM LUNG ASPIRATION MUST BE WEIGHED AGAINST TOX WHEN(ING 5)
RTECS #:9999999ZZ

Ingred Name:ING 4: CONSIDERING EMPTYING THE STOMACH. NO SPECIFIC
    ANTIDOTE. SUPPORTIVE CARE. TREATMENT BASED ON JUDGMENT OF (ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5: THE PHYSICIAN IN RESPONSE TO REACTIONS OF THE
    PATIENT.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50 (ORAL,RAT) >4000 MG/KG
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:YES	 OSHA:NO
Health Hazards Acute and Chronic:EYE: MAY CAUSE MODERATE IRRITATION
    W/CORNEAL INJURY. VAPORS MAY IRRITATE EYES. MAY CAUSE LACRIMATION
    (TEARS).SKIN: PROLONGED EXPOSURE MAY CAUSE SKIN IRRITATION.
    REPEATED EXPOSURE MAY CAUSE SKIN BURNS.  SKIN ABSORPTION: A SINGLE
    PROLONGED EXPOSURE IS NOT LIKELY TO RESULT IN THE MATERIAL BEING
    ABSORBED(EFTS OF OVEREXP)
Explanation of Carcinogenicity:STYRENE: GROUP 2B (IARC)
Effects of Overexposure:HLTH HAZ: THRU SKIN IN HARMFUL AMTS. INGEST:
    SINGLE DOSE ORAL TOX IS BELIEVED TO BE LOW. IF ASPIRATED (LIQ
    ENTERS THE LUNG), MAY BE RAPIDLY ABSORBED THRU THE LUNGS & RESULT
    IN INJURY TO OTHER BODY SYS TEMS. INHAL: EXCESSIVE VAPOR CONC ARE
    ATTAINABLE	&(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:EYE: IRRIGATE W/FLOWING WATER IMMEDIATELY & CONTINUOUSLY FOR
    AT LEAST 15 MIN. CONSULT MEDICAL PERSONNEL. SKIN: WASH OFF IN
    FLOWING WATER/SHOWER. INGEST: DO NOT INDUCE VOMITING. CALL MD
    AND/OR TRANSPOR T TO EMERGENCY FACILITY IMMEDIATELY. INHAL: REMOVE
    TO FRESH AIR. IF NOT BREATHING, GIVE MOUTH-TO-MOUTH RESUSCITATION.
    IF BREATHING IS DIFFICULT, GIVE O*2. CALL MD. NOTE TO MD: THE
    DECISION OF (ING 3)

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:70.0F,21.1C
Lower Limits:SEE INGRED 1
Upper Limits:SEE INGRED 1
Extinguishing Media:WATER FOG, FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
    PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:UPON EXPOSURE TO HEAT OR FLAME, AN
    EXOTHERMIC REACTION CAN DEVELOP, FOLLOWED BY DECOMPOSITION OF
    PRODUCT. KEEP VAPORS AWAY FROM POSSIBLE IGNITION SOURCES.

==================  Accidental Release Measures  ==================

Spill Release Procedures:TREAT AS FLAMM LIQ; KEEP HEAT/FLAME/OR SPARK
    PRODUCING EQUIP AWAY.  PROT PERSONNEL FROM STYRENE VAPS. SOAK UP
    SPILLS IN ABSORB MATL SUCH AS SAND AND COLLECT IN SUITABLE
    CONTAINERS. RESIDUAL RESIN MAY  BE REMOVED USING STEAM OR HOT SOAPY
    H*2O. (ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:PRACTICE GOOD CARE & CAUTION TO AVOID
    SKIN/EYE CNTCT & TO AVOID BRTHG VAPS.FOR ADDTNL PREC, SEE DOW
    BULLETIN, DERKANE(R)VINYL ESTER RESINS-FABRICATING
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW
    EXPOSURE GUIDLINE. WHEN RESPIRATORY PROT IS REQUIRED FOR CERTAIN
    OPERATIONS, USE NIOSH/MSHA APPRVD AIR-PURIFYING RESPIRATOR. IF
    VAPOR EXPOSURE CAUSES EYE  DISCOMFORT, USE A FULL-FACE RESP.
Ventilation:PROVIDE GENERAL AND/OR LOCAL EXHAUST VENTILATION TO CONTROL
    AIRBORNE CONCENTRATIONS BELOW THE EXPOSURE GUIDELINES.
Protective Gloves:IMPERVIOUS GLOVES
Eye Protection:CHEMICAL WORKERS GOGGLES 
Other Protective Equipment:USE PROT CLTHG IMPERVIOUS TO THIS MATL.
    SELECTION OF SPECIFIC ITEMS SUCH AS BOOT, APRON, OR FULL-BODY SUIT.
Work Hygienic Practices:EYEWASH FOUNTAINS SHOULD BE IN IMMED WORK AREA.
Supplemental Safety and Health
EFTS OF OVEREXP: COULD BE HAZ ON SINGLE EXPOSURE. SIGNS AND SYMPTOMS OF
    EXCESSIVE EXPOSURE MAY BE ANESTHETIC OR NARCOTIC EFTS. EXCESSIVE
    EXPOSURE MAY CAUSE IRRIT TO UPPER RESPIRATORY TRACT. SYSTEMIC & 
    OTHER EFTS: RPTD EXCESSIVE EXPOSURES TO HIGH AMTS MAY CAUSE CNS,
    LIVER, KIDNEY EFTS AND RESP OR EYE IRRITATION.

==================  Physical/Chemical Properties  ==================

HCC:F3
Boiling Pt:B.P. Text:SEE ING 1
Vapor Pres:SEE ING 1
Vapor Density:SEE ING 1
Spec Gravity:1.025
Solubility in Water:INSOLUBLE
Appearance and Odor:REDDISH, VISCOUS LIQUID. PUNGENT STYRENE ODOR.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS.
Stability Condition to Avoid:AVOID STORAGE IN DIRECT SUNLIGHT AND AT
    TEMPERATURES ABOVE 120 F, 49 C.
Hazardous Decomposition Products:PYROLYSIS PRODUCTS SUCH AS CO.
Conditions to Avoid Polymerization:AVOID CNTCT W/METAL SALTS SUCH AS
    FERRIC & ALUMINUM CHLORIDES, UNINTENDED CONTACT W/PEROXIDES, &
    DEPLETION OF (ING 10)

====================  Disposal Considerations  ====================

Waste Disposal Methods:RESIN CAN BE DISPOSED OF THROUGH BURNING IN AN
    ADEQUATE INCINERATOR OR BURYING IN AN APPROVED LANDFILL IN
    ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.

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 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
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