NATIONAL INSTITUTE OF STANDARDS & TECHNOLOGY -- PHOSPHORUS SPECTROMETRIC STANDARD SOLUTION, 3139 -- 6630-00N056826
=====================  Product Identification  =====================

Product ID:PHOSPHORUS SPECTROMETRIC STANDARD SOLUTION, 3139
MSDS Date:05/01/1991
FSC:6630
NIIN:00N056826
MSDS Number: CDTJH
=== Responsible Party ===
Company Name:NATIONAL INSTITUTE OF STANDARDS & TECHNOLOGY
Address:E BLDG 128 RT 2 QUINCY ORCHARD RD
City:GAITHERSBURG
State:MD
ZIP:20899
Country:US
Info Phone Num:301-975-2019
Emergency Phone Num:301-975-2000
CAGE:9Y292
=== Contractor Identification ===
Company Name:NATIONAL INSTITUTE OF STANDARDS & TECH
Address:RT 270 & QUINCY ORCHARD E BLDG 128
Box:City:GAITHERSBURG
State:MD
ZIP:20899
Country:US
Phone:301-975-6439
CAGE:9Y292

=============  Composition/Information on Ingredients  =============

Ingred Name:HYDROCHLORIC ACID (SARA 302/313) (CERCLA). BP: -121F,-85C.
    SPEC GRAV: 1.189. VP: 4 @ 17.8C. MP:-174F,-114C. (ING 2)
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: 0.05%
OSHA PEL:5 PPM, C
ACGIH TLV:5 PPM, C
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:ING 1: SOL IN H*2O: COMPLETE. APPEAR/ODOR: CLEAR, COLORLESS
    LIQUID WITH PUNGENT, IRRITATING ODOR.
RTECS #:9999999ZZ
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:AMMONIUM PHOSPHATE MONOBASIC; (AMMONIUM ORTHOPHOSPHATE).
    SPEC GRAV: 1.803. SOL IN H*2O: MODERALTELY SOLUBLE; (ING 4)
CAS:7722-76-1
Fraction by Wt: 3.71%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:ING 3: ONE GRAM DISSOLVES IN APPROXIMATELY 2.5 ML H*2O.
    APPEAR/ODOR: BRILLIANT WHITE CRYSTALS OR POWDER.
RTECS #:9999999ZZ
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:PHOSPHOROUS (YELLOW); (PHOSPHORUS) (SARA 302/313) (CERCLA).
     BP: 536F,280C.  SPEC GRAV: 1.83.  MP: 111F,44C. (ING 6)
CAS:7723-14-0
RTECS #:TH3500000
Fraction by Wt: 1%
OSHA PEL:0.1 MG/M3
ACGIH TLV:0.02 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:ING 5: SOL IN H*2L: INSOLUBLE.  APPEAR/ODOR: COLORLESS OR
    WHITE TRANSPARENT CRYSTALLINE SOLID W/WAXY APPEARANCE; (ING 7)
RTECS #:9999999ZZ
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:ING 6: DARKENS ON EXPOSURE TO LIGHT.
RTECS #:9999999ZZ
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:EFTS OF OVEREXP: EXTREMELY HAZ TO EYES & CAN DMG SEVERELY.
    IF PHOSPHORUS IS INGESTED, CAN BE ABSORBED FROM GI (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8:TRACT OR THRU LUNGS. ABSORPTION OF TOX QTYS OF
    PHOSPHORUS HAS ACUTE EFT ON LIVER & IS ACCOMPANIED BY VOMIT(ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9: & MARKED WEAK. CONTINUED ABSORPTION OF SM AMTS OF
    PHSOPHORUS CAN RSLT IN NECROSIS OF MANDIBLE OF JAW/JAW (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10:BONE KNOWN AS PHOSSY-JAW. CONTINUED EXPOS THRU LUNGS
    & GI TRACT CAN CAUSE CHRONIC POISONING. SYMPS:WEAK, (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11: ANEMIA, LOSS OF APPETITE, GI WEAK & PALLOR. PRLNGD
    EXPOS CAN ALSO CAUSE CHGS IN LONG BONES & MAY CAUSE (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: THEM TO BECOME BRITTLE LEADING TO SPONT FRACTURES.
    PHOSPHORUS ALSO HAS ADVERSE EFT ON TEETH. HCL CAN (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13:CAUSE IRRIT OF SKIN & THROAT, CHOKING & BURNING
    SENSATIONS, COUGH, WHEEZING, LARYNGITIS, SHORTNESS OF (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14:BRTH, HDCH, NAUS & VOMIT. PHOSPHORUS & ITS CMPDS CAN
    CAUSE IRRIT OF EYES, NOSE, MUC MEMBS & UPPER RESP (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15:TRACT. WEAK, ANEMIA, LOSS OF APPETITE, VOMIT & LOSS
    OF BONE AGILITY CAN ALSO OCCUR. STOM PAINS & DIARR (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16:ARE ALSO SIGNS OF EXPOS. TARGET ORGANS:HCL:LUNGS,
    SKIN & URT. P & CMPDS:SKIN, EYES, MUC MEMBS, LIVER, (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17: URT & SKELETAL SYS. NOTE:PERIODIC DENTAL EXAMS
    SHOULD BE PROVIDED FOR WORKERS HNDLG MATLS CONTAINING PHOSPHORUS.
RTECS #:9999999ZZ

Ingred Name:FIRST AID: NOT BRTHG, GIVE ARTF RESP. CONTACT MED
    ASSISTANCE IF NECESSARY. INGEST: IF CONSCIOUS, GIVE 2-3 (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19: GLASSES OF WATER THEN MILK OF MAGNESIA OR
    LIMEWATER. CONTACT MED ASSISTANCE IF NECESSARY.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: OF WATER. CONTAIN LARGE SPILLS. COLLECT OR
    FLUSH WATER TO HOLDING AREA FOR NEUTRALIZATION. DO NOT (ING 22)
RTECS #:9999999ZZ

Ingred Name:ING 21: FLUSH DIRECTLY TO SEWER OR SURFACE WATERS.
RTECS #:9999999ZZ

Ingred Name:EYE PROT: & FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:HYDROCHLORIC ACID IS EXTREMELY
    DESTRUCTIVE TO THE TISS OF MUC MEMBS, UPPER RESP TRACT, EYES &
    SKIN. INHAL OF GAS CONCS MODERATELY ABOVE TLV CAN DMG TEETH &
    IRRITATE NASAL PASSAGES. INHAL MAY BE FATAL  AS RSLT OF SPASM,
    INFLAM & EDEMA OF LARYNX & BRONCHI, CHEM PNEUM & PULM EDEMA. HCL
    CAN ALSO CAUSE SEV (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: BURNS. PHOSPHORUS & ITS CMPDS ARE
    HIGHLY TOX VIA DERMAL, ORAL, SUBCUTANEOUS & INHAL ROUTES. IF
    COMBUST OCCURS IN CONFINED SPACE, IT WILL REMOVE OXYGEN CAUSING ATM
    TO BECOME INSUFFICIENT TO S USTAIN LIFE. HIGH CONCS OF VAPS ARE
    IRRIT TO NOSE, EYES, THROAT, LUNGS & MUC MEMBS. THESE SUBSTANCES
    ARE (ING 8)
Medical Cond Aggravated by Exposure:BURNS, DERMATITIS, LARYNGEAL SPASM,
    PULMONARY EDEMA CAN BE AGGRAVATED BY HCL.

=======================  First Aid Measures  =======================

First Aid:SKIN:REMOVE CONTAMD SHOES & CLTHG. RINSE AFFECTED AREA W/LG
    AMTS OF WATER FOLLOWED BY WASHING AREA W/SOAP & WATER. CNTCT MED
    ASSISTANCE IF NEC. EYES: IMMED FLUSH EYES, INCL UNDER EYELIDS
    W/COPIOUS AMT S OF WATER FOR @ LST 15 MIN. ASSURE ADEQ FLUSHING OF
    EYES BY SEPARATING EYELIDS W/FINGERS. CNTCT MED ASSISTANCE IF NEC.
    INHAL: REMOVE TO FRESH AIR. IF BRTHG IS DFCLT, GIVE OXYGEN; IF
    VICTIM IS(ING 19)

=====================  Fire Fighting Measures  =====================

Extinguishing Media:SELECT EXTINGUISHING MEDIA APPROP TO SURROUNDING
    FIRE. USE WATER SPRAY TO COOL FIRE-EXPOSED CNTNRS TO PREVENT
    RUPTURE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:ACID MIX IS NON-FLAM BUT ACID CAN REACT
    W/MANY METALS TO PRDCE FLAM HYDROGEN GAS. NEUT ACID W/LIMESTONE,
    SLAKED LIME OR SODA ASH TO MIN FORM OF POTNTLY (SUPDAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:NOTIFY SFTY PERS OF LARGE LEAKS/SPILLS. REMOVE
    SOURCES OF IGNIT; H*2 MAY BE GENERATED. PROVIDE OPTIMUM VENT. SM
    SPILLS CAN BE COVERED W/EXCESS OF MIX OF SODA ASH & SLAKED LIME TO
    NEUT SLURRY PICKED UP  FOR LANDFILL BURIAL OR FLUSHED W/LG AMTS
    (ING 21)
Neutralizing Agent:LIMESTONE, SODA ASH OR SLAKED LIME.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE CONTAINERS IN A CLEAN, COOL,
    WELL-VENTILATED AREA OUT OF DIRECT SUNLIGHT AND AWAY FROM OXIDIZING
    AGENTS AND SOURCES OF HEAT.
Other Precautions:PROVIDE EMERGENCY NEUTRALIZATION MATERIALS AND
    EQUIPMENT NEAR STORAGE AND AREAS OF USE.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
    EXPOSURE OF CONCERN .
Ventilation:PROVIDE ADEQUATE EXHAUST VENTILATION TO MEET TLV
    REQUIREMENTS.
Protective Gloves:RUBBER GLOVES OR GAUNTLETS.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 23)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER FULL
    PROT CLTHG & EQUIP TO PVNT BODY CNTCT; APRONS, LONG-SLEEVED SHIRTS,
    ETC.
Work Hygienic Practices:CNTCT LENSES POSE SPEC PROB; SOFT LENSES MAY
    ABSORB IRRITANTS & ALL LENSES CONCENTRATE THEM. DO NOT WEAR THEM IN
    LAB.
Supplemental Safety and Health
EXPLO HAZ: EXPLO HYDROGEN GAS. CONTACT NEHC FOR A COMPLETE LIST OF
    CHEMS THAT REACT EXPLO W/PHOSPHORUS & ITS CMPDS . MATL TO AVOID:
    MATLS. PHOSPHORUS & ITS CMPDS SHOULD BE KEPT FROM OXIDIZING AG
    ENTS. FOR A COMPLETE LIST OF MATLS TO AVOID CONTACT NEHC .

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:SEE INGS
Melt/Freeze Pt:M.P/F.P Text:SEE INGS
Vapor Pres:SEE INGS
Spec Gravity:SEE INGS
Solubility in Water:SEE INGREDIENTS
Appearance and Odor:SEE INGREDIENTS

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
HCL DISSOLVES EXOTHERMICALLY IN WATER TO FORM AQ HYDROCHLORIC ACID. IT
    CAN ALSO REACT EXOTHERMICALLY W/MANY ORG (SUPDAT)
Stability Condition to Avoid:KEEP MIXTURE FROM EXCESSIVE HEAT.
Hazardous Decomposition Products:HCL GAS IS PRODUCED FORM THE ACID.
    HIGHLY TOXIC FUMES OF PO*X ARE PRODUCED FROM PHOSPHORUS AND ITS
    COMPOUNDS.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSE OF THE ACID MIXTURE VIA LICENSED
    CONTRACTOR OR NEUTRALIZE WITH LIMESTONE, SODA ASH OR SLAKED LIME.
    FLUSHING TO SEWER DEPENDS ON ALLOWABLE NEUTRAL SALT CONCENTRATIONS
    AND EFFLUENT WATER. FOLLOW	ALL FEDERAL, STATE AND LOCAL
    REGULATIONS.

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 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.